Отрывок: Steady-state silicon monoxide cation (SiO+) super rotors with rotational quantum numbers N up to 170 were prepared in a linear quadrupole trap by means of optical pumping. Our measurements showed that the rate of reaction of SiO+ super rotors with molecular hydrogen increased by a factor of 3 compared to thermal SiO+ molecules. Quasiclassical trajectory (QCT) calculations explained the observed rate increase by a dynamic effect via coupling of SiO+ rotational motion to a reaction coord...
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dc.contributor.authorAntonov I.ru
dc.contributor.authorVenkataramanababu S.ru
dc.contributor.authorDragan J.ru
dc.contributor.authorLi A.ru
dc.contributor.authorGuo H.ru
dc.contributor.authorOdom B.ru
dc.coverage.spatialэнергия электронной связиru
dc.coverage.spatialмолекулы супер роторыru
dc.coverage.spatialквадрупольная ловушкаru
dc.coverage.spatialоптическая накачкаru
dc.coverage.spatialquadrupole trapru
dc.coverage.spatialoptical pumpingru
dc.coverage.spatialmolecules super rotorsru
dc.coverage.spatialelectronic bonding energyru
dc.creatorAntonov I., Venkataramanababu S., Dragan J., Li A., Guo H., Odom B.ru
dc.date.accessioned2022-10-06 14:29:37-
dc.date.available2022-10-06 14:29:37-
dc.date.issued2022ru
dc.identifierRU\НТБ СГАУ\488175ru
dc.identifier.citationDynamic rotational effect in reaction of SiO+ super rotors with H2 / I. Antonov, S. Venkataramanababu, J. Dragan, A. Li, H. Guo, B. Odom // International Conference on Physics and Chemistry of Combustion and in Extreme Environments (Samara, Russia, 12-16 July 2022) / V. N. Azyazov, A. M. Mayorova. - Samara : Publishing OOO “Insoma-Press”, 2022. - P. 31.ru
dc.identifier.urihttp://repo.ssau.ru/handle/International-Conference/Dynamic-rotational-effect-in-reaction-of-SiO-super-rotors-with-H2-98898-
dc.language.isoengru
dc.sourceInternational Conference on Physics and Chemistry of Combustion and in Extreme Environments (Samara, Russia, 12-16 July 2022)ru
dc.titleDynamic rotational effect in reaction of SiO+ super rotors with H2ru
dc.typeTextru
dc.textpartSteady-state silicon monoxide cation (SiO+) super rotors with rotational quantum numbers N up to 170 were prepared in a linear quadrupole trap by means of optical pumping. Our measurements showed that the rate of reaction of SiO+ super rotors with molecular hydrogen increased by a factor of 3 compared to thermal SiO+ molecules. Quasiclassical trajectory (QCT) calculations explained the observed rate increase by a dynamic effect via coupling of SiO+ rotational motion to a reaction coord...-
Располагается в коллекциях: International Conference on Combustion Physics and Chemistry

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